Mesoporous inorganic salts with crystal defects: unusual catalysts and catalyst supports† †Electronic supplementary information (ESI) available: Scheme S1 contains reaction equation, Fig. S1–S7 contain solubility test, XRD, SEM, TEM, micropore size distribution and reaction conversion. See DOI: 10.1039/c4sc03736g Click here for additional data file.

نویسندگان

  • Xinchen Kang
  • Wenting Shang
  • Qinggong Zhu
  • Jianling Zhang
  • Tao Jiang
  • Buxing Han
  • Zhonghua Wu
  • Zhihong Li
  • Xueqing Xing
چکیده

We proposed a strategy to synthesize mesoporous inorganic salt particles using the special properties of ionic liquid (IL) mixtures, and hollow mesoporous LaF3, NdF3, and YF3 particles were synthesized and characterized using different techniques. The size of the mesopores in the salt particles was about 4 nm, and the materials were full of crystal defects. The LaF3, NdF3 and YF3 particles were used as the catalysts for the cyanosilylation reaction of benzaldehyde using trimethylsilyl cyanide, and Ru/LaF3 and Ru/NdF3, in which Ru nanocatalysts were supported on the LaF3 and NdF3 particles with mesopores, were used to catalyze hydrogenations of benzene to cyclohexane and levulinic acid (LA) to g-valerolactone (GVL). It was discovered that the activities of these catalysts were unprecedentedly high for these reactions. Detailed study showed that both the crystal defects and the mesopores in the salt particles played crucial roles for the extremely high catalytic activity.

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منابع مشابه

Methanol-to-hydrocarbons conversion over MoO3/H-ZSM-5 catalysts prepared via lower temperature calcination: a route to tailor the distribution and evolution of promoter Mo species, and their corresponding catalytic properties† †Electronic supplementary information (ESI) available: more TEM images of post-run samples, CS Chem3D Model of zeolite and external surface MoO3, images and file (.c3xml). See DOI: 10.1039/c5sc01825k Click here for additional data file. Click here for additional data file.

The supplementary data have included a full range of TEM pictures of the post-run samples, including 400 oC calcinated MoO3/H-ZSM-5 samples (coked) and the parent H-ZSM-5 (coked), showing the distribution of Mo clusters on the zeolite crystallite external surface, and the observed coke deposition upon the spreading of the Mo species. The Figures S1-S9 are the complementary of the Fig. 8 in the ...

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عنوان ژورنال:

دوره 6  شماره 

صفحات  -

تاریخ انتشار 2015